Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry
Résumé
The system laccase/mediator/dioxygen is able to trigger radical reactions with radical precursors which are not natural substrates of this enzyme. The radical generation has been accomplished by single electron transfer oxidation of a 1,3-dicarbonyl precursor. The process is exemplified with a radical cascade.
Domaines
Chimie organique
Origine : Fichiers produits par l'(les) auteur(s)
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